Item type |
紀要論文(ELS) / Departmental Bulletin Paper(1) |
公開日 |
1987-09-01 |
タイトル |
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言語 |
en |
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タイトル |
HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE |
言語 |
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言語 |
eng |
資源タイプ |
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資源タイプ識別子 |
http://purl.org/coar/resource_type/c_6501 |
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資源タイプ |
departmental bulletin paper |
ページ属性 |
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内容記述タイプ |
Other |
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内容記述 |
P(論文) |
記事種別(英) |
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en |
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ABSTRACT |
論文名よみ |
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その他のタイトル |
HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE |
著者名よみ |
ハタケヤマ, シロウ /
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著者名(英) |
HATAKEYAMA, Shiro
LEU, Ming-Taun
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著者所属(英) |
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en |
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National Institute for Environmental Studies |
著者所属(英) |
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en |
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Jet Propulsion Laboratory, California Institute of Technology |
抄録(英) |
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内容記述タイプ |
Other |
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内容記述 |
Reactions of chlorine nitrate (ClONO_2) with HCl and H_2O have been investigated using a 320-L Pyrex chamber and long-path FT-IR spectroscopy. Both reactions showed highly heterogeneous nature. Obtained upper limit rate constants fot homogeneous reactions were 8.4×(10)^<-21> and 3.4×(10)^<-21>(cm)^3 molec^<-1>s^<-1> for ClONO_2+HCl and ClONO_2+H_2O, respectively, at 296±2K at 730 torr total pressure. The yield of HNO_3 from both the reactions was 1.05±0.09 and 0.86±0.08,respectively. Formation of HOCl was confirmed in the latter reaction. No synergistic effect between HCl and H_2O was observed for the reaction with ClONO_2. The kinetic behavior of the reaction ClONO_2+H_2O was well described by simple first-order kinetics while the behavior of the reaction ClONO_2+HCl was found to obey the Langmuir adsorption isotherm. |
雑誌書誌ID |
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収録物識別子タイプ |
NCID |
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収録物識別子 |
AA10756213 |
書誌情報 |
Proceedings of the NIPR Symposium on Polar Meteorology and Glaciology
巻 1,
p. 148,
発行日 1987-09
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