{"created":"2023-07-25T11:01:29.737795+00:00","id":3536,"links":{},"metadata":{"_buckets":{"deposit":"b721979d-63f2-4c2b-93ae-627f9d3b3c0c"},"_deposit":{"created_by":4,"id":"3536","owners":[4],"pid":{"revision_id":0,"type":"depid","value":"3536"},"status":"published"},"_oai":{"id":"oai:nipr.repo.nii.ac.jp:00003536","sets":["1259:1260:1262:524:525"]},"author_link":["4895","4894","4896"],"item_1_alternative_title_5":{"attribute_name":"論文名よみ","attribute_value_mlt":[{"subitem_alternative_title":"HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE"}]},"item_1_biblio_info_14":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1987-09","bibliographicIssueDateType":"Issued"},"bibliographicPageStart":"148","bibliographicVolumeNumber":"1","bibliographic_titles":[{"bibliographic_title":"Proceedings of the NIPR Symposium on Polar Meteorology and Glaciology"}]}]},"item_1_creator_7":{"attribute_name":"著者名よみ","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"ハタケヤマ, シロウ /"}],"nameIdentifiers":[{}]}]},"item_1_creator_8":{"attribute_name":"著者名(英)","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"HATAKEYAMA, Shiro","creatorNameLang":"en"}],"nameIdentifiers":[{}]},{"creatorNames":[{"creatorName":"LEU, Ming-Taun","creatorNameLang":"en"}],"nameIdentifiers":[{}]}]},"item_1_description_1":{"attribute_name":"ページ属性","attribute_value_mlt":[{"subitem_description":"P(論文)","subitem_description_type":"Other"}]},"item_1_description_12":{"attribute_name":"抄録(英)","attribute_value_mlt":[{"subitem_description":"Reactions of chlorine nitrate (ClONO_2) with HCl and H_2O have been investigated using a 320-L Pyrex chamber and long-path FT-IR spectroscopy. Both reactions showed highly heterogeneous nature. Obtained upper limit rate constants fot homogeneous reactions were 8.4×(10)^<-21> and 3.4×(10)^<-21>(cm)^3 molec^<-1>s^<-1> for ClONO_2+HCl and ClONO_2+H_2O, respectively, at 296±2K at 730 torr total pressure. The yield of HNO_3 from both the reactions was 1.05±0.09 and 0.86±0.08,respectively. Formation of HOCl was confirmed in the latter reaction. No synergistic effect between HCl and H_2O was observed for the reaction with ClONO_2. The kinetic behavior of the reaction ClONO_2+H_2O was well described by simple first-order kinetics while the behavior of the reaction ClONO_2+HCl was found to obey the Langmuir adsorption isotherm.","subitem_description_type":"Other"}]},"item_1_source_id_13":{"attribute_name":"雑誌書誌ID","attribute_value_mlt":[{"subitem_source_identifier":"AA10756213","subitem_source_identifier_type":"NCID"}]},"item_1_text_10":{"attribute_name":"著者所属(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"National Institute for Environmental Studies"},{"subitem_text_language":"en","subitem_text_value":"Jet Propulsion Laboratory, California Institute of Technology"}]},"item_1_text_3":{"attribute_name":"記事種別(英)","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"ABSTRACT"}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"1987-09-01"}],"displaytype":"detail","filename":"KJ00000767744.pdf","filesize":[{"value":"95.7 kB"}],"format":"application/pdf","licensetype":"license_6","mimetype":"application/pdf","url":{"url":"https://nipr.repo.nii.ac.jp/record/3536/files/KJ00000767744.pdf"},"version_id":"9c5bfe8e-0654-4676-a532-04b7c304694b"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE","subitem_title_language":"en"}]},"item_type_id":"1","owner":"4","path":["525"],"pubdate":{"attribute_name":"公開日","attribute_value":"1987-09-01"},"publish_date":"1987-09-01","publish_status":"0","recid":"3536","relation_version_is_last":true,"title":["HETEROGENEOUS REACTIONS RELATED TO ANTARCTIC OZONE HOLE"],"weko_creator_id":"4","weko_shared_id":4},"updated":"2023-07-25T14:34:00.140183+00:00"}